Photo credits: ScenTree SAS
General Presentation
-
CAS N° :
122-78-1 -
EINECS number :
204-574-5 -
FEMA number :
2874 -
FLAVIS number :
5,03
-
JECFA number :
1002 -
Volatility :
Base -
Price Range :
€€€
Physico-chemical properties
-
Appearance :
Colorless liquid -
Density :
1,03 -
Refractive Index @20°C :
1,525 - 1,545 -
Optical rotation :
Donnée indisponible. -
Vapor pressure :
0,3675 mmHg @25°C -
Flash Point :
68°C (154,4°F)
-
Molecular formula :
C8H8O -
Molecular Weight :
120,15 g/mol -
Log P :
1,54 -
Fusion Point :
-10°C (14°F) -
Boiling Point :
193°C (379,4°F) -
Detection Threshold :
4 ppb (0,0000004%)
Chemistry & Uses
Uses in perfumery :
Phenyl Acetaldehyde is used in rosy floral notes, citrus or leather notes.
Year of discovery :
1908
Natural availability :
Phenyl Acetaldehyde is present in many flowers such as chicory or flower of Lecythis usitata in Brazil, from which it can be extracted.
Isomerism :
Phenyl Acetaldehyde does not have any isomer used in perfumery.
Synthesis precursor :
Phenyl Acetaldehyde is a precursor to the synthesis of a Schiff base by reaction with Methyl Anthranilate. This molecule has a pinkish, green, honeydew and mandarin smell. Furthermore, a reaction with methanol in an acid medium synthesizes Viridine®.
Synthesis route :
Phenyl Acetaldehyde can be synthesized during the vapor phase isomerization of styrene oxide, in the presence of aluminum silicate, or from phenylethane-1,2-diol, always during the vapor phase and always in presence of aliminum silicate, used as catalysts.
Stability :
Aldehydes may form diethylacetals in alcoholic perfumes, with no real impact on their smell
Has a great capacity of polymerisation
Most of the time, the occurrence of a benzenic cycle in a molecule causes a coloration of this molecule through time
Other comments :
Phenyl Acetaldehyde is often marketed diluted in Phenyl Ethyl Alcohol. It has a more honeyed and less green facet than the latter.
Labelling
Allergens :
This ingredient does not contain any allergen.
Signal word :
Warning
Hazard pictograms :
Precautionary statements :
| HAZARD | PRECAUTION |
|---|---|
| H302 Harmful if swallowed.
H317 May cause an allergic skin reaction. |
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302 + P352 IF ON SKIN: Wash with plenty of water/… P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. |
IFRA
IFRA 51th :
This ingredient is restricted by the 51th amendment
-
Restriction type :
RESTRICTION -
Cause of restriction :
DERMAL SENSITIZATION AND SYSTEMIC TOXICITY -
Amendment :
49
Quantitative limit on the use :
| Cat.1 | Cat.2 | Cat.3 | Cat.4 |
Cat.5
A
B
C
D
|
Cat.6 | |||
|---|---|---|---|---|---|---|---|---|
| 0,045 % | 0,014 % | 0,27 % | 0,25 % |
0,064 %
0,064 %
0,064 %
0,021 %
|
||||
|
Cat.5
A
B
C
D
|
Cat.6 | |||||||
|
0,064 %
0,064 %
0,064 %
0,021 %
|
0,15 % | |||||||
|
Cat.7
A
B
|
Cat.8 | Cat.9 |
Cat.10
A
B
|
Cat.11
A
B
|
Cat.12 | |||
|
0,52 %
0,52 %
|
0,021 % | 0,49 % |
0,49 %
1,8 %
|
0,021 %
0,021 %
|
||||
|
Cat.10
A
B
|
Cat.11
A
B
|
Cat.12 | ||||||
|
0,49 %
1,8 %
|
0,021 %
0,021 %
|
No Restriction | ||||||
Disclaimer :
ScenTree is solely responsible for the information provided here.
To learn more about IFRA's standards : https://ifrafragrance.org/safe-use/library
