Photo credits: ScenTree SAS
Helional®
Marine > Ozonic > Juicy Fruits
Aquanal® ; Heliobouquet® ; Heliogan® ; 3-(1,3-benzodioxol-5-yl)-2-methylpropanal ; Cetonial ; Floramelon ; Florial ; Neohelial ; Heliofresh ; Heliolan ; Helionix ; Heliopropanal ; Alpha-methyl-1,3-benzodioxole-5-propanal ; Alpha-methyl-1,3-benzodioxole-5-propionaldehyde ; 2-methyl-3-(3,4-methyenedioxyphenyl)propionaldehyde ; Alpha-methyl-3,4-(methylene dioxy) hydrocinnamaldehyde ; 3-(3,4-methylenedioxyphenyl)-2-methylpropanal ; Neohelial ; Ocean propanal ; Tropional
Photo credits: ScenTree SAS
| Company | Ingredient Name | Learn more | Naturality | Certifications | MOQ | Purity |
|---|---|---|---|---|---|---|
|
HELION
HEL-1
|
Discover | - | 10 grs | 98.0 - 100.0 | |
|
Helional - 30 Gr | Discover | - | 30grs | - | |
|
SCHIFF HELIONAL
85710
|
Discover | Molecule | - | - | |
|
Helionix/Helional | Discover | Synthetic Aroma Chemicals | - | - |
HEL-1
85710
General Presentation
-
CAS N° :
1205-17-0 -
EINECS number :
214-881-6 -
FEMA number :
4599 -
FLAVIS number :
Donnée indisponible.
-
JECFA number :
2212 -
Volatility :
Heart/Base -
Price Range :
€€
Physico-chemical properties
-
Appearance :
Colorless liquid -
Density :
1,163 -
Refractive Index @20°C :
1,531 - 1,536 -
Optical rotation :
Donnée indisponible. -
Vapor pressure :
0,0003 mmHg @23°C 0,003 mmHg @25°C -
Flash Point :
100°C (212°F)
-
Molecular formula :
C11H12O3 -
Molecular Weight :
192,21 g/mol -
Log P :
1,37 -
Fusion Point :
Donnée indisponible. -
Boiling Point :
282°C (539,6°F) -
Detection Threshold :
Donnée indisponible.
Chemistry & Uses
Uses in perfumery :
Helional® is used in marine and juicy fruits accords, or for a light and ozonic note. Gives volume to a perfume or accord. Often used in functional fragrance.
Year of discovery :
Discovered in 1958. Patent N°3,008,968 published in february,11 1958 by Muus G.J. Beets and Harm van Essen for IFF
Natural availability :
Helional® is not available in its natural state.
Isomerism :
Helional® has an asymmetric carbon. The racemic mixture of the two enantiomers of the molecule is most often used. The (R) isomer is responsible for a fairly sweet aldehyde lily of the valley smell, while the (S) isomer is more ozonic, green and fruity.
Synthesis precursor :
May form a Schiff base with Methyl Anthranilate, called "Corps Oranger".
Synthesis route :
Helional® can be synthesized from Heliotropin by a condensation reaction with propanal, followed by a catalytic hydrogenation of the double bond that has formed.
Stability :
Aldehydes may form diethylacetals in alcoholic perfumes, with no real impact on their smell.
Can react with Methyl Anthranilate to form a Schiff base that colors through time.
Other comments :
The smell of Helional® is less aldehydic than Cyclamen Aldehyde, less fruity than Melonal® and less marine than Calone®. Helional® is also less powerful than these three compounds.
Labelling
Allergens :
This ingredient does not contain any allergen.
Signal word :
Warning
Hazard pictograms :
Precautionary statements :
| HAZARD | PRECAUTION |
|---|---|
| H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects. |
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P391 Collect spillage. |
IFRA
IFRA 51th :
This ingredient is restricted by the 51th amendment
-
Restriction type :
RESTRICTION -
Cause of restriction :
DERMAL SENSITIZATION AND SYSTEMIC TOXICITY -
Amendment :
49
Quantitative limit on the use :
| Cat.1 | Cat.2 | Cat.3 | Cat.4 |
Cat.5
A
B
C
D
|
Cat.6 | |||
|---|---|---|---|---|---|---|---|---|
| 0,12 % | 0,25 % | 0,039 % | 2,6 % |
0,39 %
0,077 %
0,077 %
0,026 %
|
||||
|
Cat.5
A
B
C
D
|
Cat.6 | |||||||
|
0,39 %
0,077 %
0,077 %
0,026 %
|
0,62 % | |||||||
|
Cat.7
A
B
|
Cat.8 | Cat.9 |
Cat.10
A
B
|
Cat.11
A
B
|
Cat.12 | |||
|
0,077 %
0,077 %
|
0,026 % | 0,15 % |
0,15 %
0,62 %
|
0,026 %
0,026 %
|
||||
|
Cat.10
A
B
|
Cat.11
A
B
|
Cat.12 | ||||||
|
0,15 %
0,62 %
|
0,026 %
0,026 %
|
12 % | ||||||
Disclaimer :
ScenTree is solely responsible for the information provided here.
To learn more about IFRA's standards : https://ifrafragrance.org/safe-use/library
