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DL-citronellyl acetate

Floral > Rosy > Green Fruits > Aquatic

Citronellyl acetate ; 3,7-dimethyloct-6-enyl acetate ; acetate de 3,7-dimethyloct-6-enyl ; Citronellyl ethanoate ; Acetic acid citronellyl ester ; Citronellol acetate ; 3,7-dimethyloct-6-enol acetate ; 3,7-dimethyloct-6-enyl ethanoate ; 3,7-dimethyloct-6-enol ethanoate

Photo credits: ScenTree SAS

Ingredient Name	Learn more	Naturality	MOQ	Purity
Citronellyl Acetate	Discover	Molecule	-	-
CITRONELLYL ACETATE CIAR-1	Discover	-	10 grs	96.0 - 100.0
CITRONELLYL ACETATE DRT 900791	Discover	Molecules	-	-
Acetate de Citronellyle - 30 Gr	Discover	-	30grs	-
Citronellyl Acetate 30035076	Discover	Molecule	-	-
Citronellyl Acetate BMBcert™ 30786719	Discover	Molecule	-	-
Citronellyl Acetate	Discover	Synthetic Aroma Chemicals	-	-

Citronellyl Acetate

CITRONELLYL ACETATE

CIAR-1

CITRONELLYL ACETATE DRT

900791

Acetate de Citronellyle - 30 Gr

Citronellyl Acetate

30035076

Citronellyl Acetate BMBcert™

30786719

Citronellyl Acetate

General Presentation

CAS N° :
150-84-5
EINECS number :
205-775-0
FEMA number :
2311
FLAVIS number :
9,012

JECFA number :
57
Volatility :
Head/Heart
Price Range :
€€

Physico-chemical properties

Appearance :
Colorless liquid
Density :
0,891
Refractive Index @20°C :
1,440 - 1,450
Optical rotation :
Donnée indisponible.
Vapor pressure :
0,0194 mmHg @23°C 0,0135 mmHg @25°C
Flash Point :
93°C (199,4°F)

Molecular formula :
C₁₂H₂₂O₂
Molecular Weight :
198,31 g/mol
Log P :
4,22
Fusion Point :
Donnée indisponible.
Boiling Point :
240°C (464°F)
Detection Threshold :
Donnée indisponible.

Chemistry & Uses

Uses in perfumery :

Citronellyl acetate is used for a fruity note in rose, lily of the valley and lavender accords for example.

Year of discovery :

Data not available.

Natural availability :

Citronellyl acetate is naturally present in Lemongrass EO, Geranium EO and Rose de Mai Absolute, and therefore is extractable in order to obtain natural Citronellyl acetate.

Isomerism :

The asymmetric carbon of Citronellol gives it two different smells if its enantiomers are separated: the (R)-(+)-Citronellyl acetate is fruity and rosy, while the (S)-(-)-Citronellyl acetate is more aldehydic, dirty and lemony. In perfumery, those two enantiomers can be used separately. In most cases, a mixture of the two is used. Menthanyl acetate, Verdox® and Vertenex® are constitutional isomers of Citronellyl acetate. However, Menthanyl acetate is much more reminiscent of Bergamot EO, and Verdox® and Vertenex® are woodier.

Synthesis precursor :

Citronellyl acetate is not a precursor to the synthesis of another compound of olfactory interest.

Synthesis route :

Citronellyl acetate can be synthesized by an esterification reaction between Citronellol and acetic acid or acetic anhydride, in an acid medium. It can also be synthesized from 3,7-dimethylocta-1,6-diene, obtained naturally by pyrolysis of alpha-Pinene. This synthesis is made in three steps: a Markovnikov addition reaction using hydrochloric acid, a Kharasch reaction, also called anti-Markovnikov reaction, with hydrobromic acid, followed by an acetolysis reaction using sodium ethanoate.

Stability :

acetates may form acetic acid through time

Other comments :

Citronellyl acetate has a less green apple note than Geranyl acetate or Neryl acetate. May contain traces of Citronellol and/or Geraniol and therefore a check must be made as it becomes a possible allergen.

Labelling

Allergens :

This ingredient does not contain any allergen.

Signal word :

Warning

Hazard pictograms :

Precautionary statements :

HAZARD	PRECAUTION
H315 Causes skin irritation. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects.	P264 Wash ... thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P337 + P313 If eye irritation persists: Get medical advice/attention. P391 Collect spillage. P501 Dispose of contents/container to…

IFRA

IFRA 51^th :

This ingredient is restricted by the 51th amendment

Restriction type :
RESTRICTION
Cause of restriction :
DERMAL SENSITIZATION AND SYSTEMIC TOXICITY
Amendment :
51

Quantitative limit on the use :

Cat.1	Cat.2	Cat.3	Cat.4	Cat.5 A B C D		Cat.6
0,49 %	0,15 %	2,0 %	2,7 %	0,70 % 0,70 % 0,70 % 0,23 %		0,82 %
Cat.5 A B C D			Cat.6
0,70 % 0,70 % 0,70 % 0,23 %			0,82 %
Cat.7 A B		Cat.8	Cat.9	Cat.10 A B	Cat.11 A B	Cat.12
2,4 % 2,4 %		0,23 %	5,4 %	0,41 % 16 %	0,23 % 0,23 %	No restriction
Cat.10 A B	Cat.11 A B	Cat.12
0,41 % 16 %	0,23 % 0,23 %	No restriction

Annexe I :

Some regulated synthetic ingredients are found in nature and in certain proportions in natural ingredients. This presence in nature has to be taken into account when calculating limits of use recommended by the IFRA. In case you do not know these concentrations, you can use the ones estimated by the IFRA. Here they are :

List of regulated compounds contained in this ingredient
Ingredient Name	Botanical Name	CAS N°	Estimated Concentration
Juniper berry oil	Juniperus communis L.	8002-68-4	0,19
Schinus molle oil	Schinus areira L.	68917-52-2	0,14
Schinus terebenthifolius CO2 extract	Schinus terebenthifolius Raddi	949495-68-5	0,25
Basil oil, chemotype linalool	Ocimum basilicum L.	8015-73-4	0,1
Lemon oil, terpeneless	Citrus limon (L.) Osbeck	68648-39-5	1,72
Citronella oil, Ceylon type	Cymbopogon nardus (L.) Rendle	8000-29-1	0,9
Citronella oil, Java type	Cymbopogon winterianus Jowitt	8000-29-1	3
Eucalyptus citriodora oil	Corymbia citriodora (Hook.) K.D. Hill & L.A. Johnson	85203-56-1	1,81
Geranium absolute	Pelargonium graveolens l'Hertier ex Aiton	8000-46-2	0,41
Geranium oil	Pelargonium graveolens l'Hertier ex Aiton	8000-46-2	0,5
Geranium oil African	Pelargonium odoratissimum L'Heritier	8000-46-2	0,8
Ginger CO2 extract	Zingiber officinalle Roscoe	8007-08-7	0,17
Lemongrass oil, East Indian	Cymbopogon flexuosus (Nees ex Steudel) Will. Watson	8007-02-1	0,23
Balm oil	Melissa officinallis L.	8014-71-9	1,35
Nutmeg oil	Myristica fragrans Houtt.	8008-45-5	0,13
Grapefruit oil, terpeneless	Citrus x paradisi Macfad.	68916-46-1	0,31
Petitgrain lemon oil	Citrus limon (L.) Burm. f.	8048-51-9	0,2
Rose oil	Rosa x damascena Mill.	8007-01-0	0,55
Rose water stronger	Rosa x centifolia L.	8007-01-0	0,02
Rose absolute	Rosa x damascena Mill.	90106-38-0	0,13
Rose concrete	Rosa x damascena Mill.	90106-38-0	0,03
Abies alba cone oil	Abies alba Mill.	8021-27-0	0,05
Bucchu absolute, betulina	Agathosma betulina (P.J.Bergius) Pillans	84649-93-4	0,15
Citrus hystrix extract	Citrus hystrix DC	91771-50-5	0,4
Tagetes minuta oil	Tagetes minuta L.	616-989-2	0,43

Disclaimer :

ScenTree is solely responsible for the information provided here.

To learn more about IFRA's standards : https://ifrafragrance.org/safe-use/library

DL-citronellyl acetate

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General Presentation

CAS N° :

EINECS number :

FEMA number :

FLAVIS number :

JECFA number :

Volatility :

Price Range :

Physico-chemical properties

Appearance :

Density :

Refractive Index @20°C :

Optical rotation :

Vapor pressure :

Flash Point :

Molecular formula :

Molecular Weight :

Log P :

Fusion Point :

Boiling Point :

Detection Threshold :

Chemistry & Uses

Uses in perfumery :

Year of discovery :

Natural availability :

Isomerism :

Synthesis precursor :

Synthesis route :

Stability :

Other comments :

Labelling

Allergens :

Signal word :

Hazard pictograms :

Precautionary statements :

IFRA

IFRA 51th :

Restriction type :

Cause of restriction :

Amendment :

Quantitative limit on the use :

Annexe I :

Disclaimer :

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IFRA 51^th :