Methyl hexyl ketone (CAS N° 111-13-7)​

Photo credits: ScenTree SAS

Methyl hexyl ketone

Fruity > Green Fruits > Butyric > Earthy

2-Octanone ; Hexyl methyl ketone ; Laventerre ; Octan-2-one ; 2-oxo octane

Methyl hexyl ketone (CAS N° 111-13-7)​

Photo credits: ScenTree SAS



Company Ingredient Name Learn more Naturality Certifications MOQ Purity
MANE logo METHYL HEXYL KETONE
M_0067361
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Synarome logo METHYL HEXYL KETONE
341
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Tilley Distribution logo Methyl Hexyl Ketone Discover Synthetic Aroma Chemicals - -
MANE logo
METHYL HEXYL KETONE

M_0067361

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Synarome logo
METHYL HEXYL KETONE

341

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Tilley Distribution logo
Methyl Hexyl Ketone
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General Presentation

General Presentation

  • CAS N° :

    111-13-7
  • EINECS number :

    203-836-1
  • FEMA number :

    2802
  • FLAVIS number :

    7,019
  • JECFA number :

    288
  • Volatility :

    Head
  • Price Range :

    €€
Physico-chemical properties

Physico-chemical properties

  • Appearance :

    Colorless liquid
  • Density :

    0,819
  • Refractive Index @20°C :

    Donnée indisponible.
  • Optical rotation :

    Donnée indisponible.
  • Vapor pressure :

    Donnée indisponible.
  • Flash Point :

    57°C (134,6°F)
  • Molecular formula :

    C8H16O
  • Molecular Weight :

    128,21 g/mol
  • Log P :

    Donnée indisponible.
  • Fusion Point :

    -16°C (3,2°F)
  • Boiling Point :

    173°C (343,4°F)
  • Detection Threshold :

    41 ppb et 62 ppb (0,0000062%)
Chemistry & Uses

Chemistry & Uses

Uses in perfumery :

Methyl Hexyl Ketone is used in hay notes and fougere accords. Allows to enhance a cheesy aspect, especially in fruity notes.

Year of discovery :

Data not available.

Natural availability :

Methyl Hexyl Ketone is present in Lavandin EO, Ruta graveolens and several foods such as certain cheeses. Therefore, it can be extracted from Lavandin EO. However, synthetic Methyl Hexyl Ketone in most often used in perfumery.

Isomerism :

When the ketone function of Methyl Hexyl Ketone is relocated, the smell can radically change. For example, Ethyl Pentyl Ketone has a more lavender and mushroom smell. 1,3 Octenol and Aldehyde C-8 are constitutional isomers of Methyl Hexyl Ketone. Their smell is closer to mushroom or more aldehyde.

Synthesis precursor :

In contrast to its synthesis, a hydrogenation of Methyl Hexyl Ketone converts it to 2-octanol, which also has an olfactory interest.

Synthesis route :

Methyl Hexyl Ketone is synthesized by a catalytic oxidation of 2-octanol. This oxidation can be done in the presence of sodium hypochlorite at a high temperature, for example.

Stability :

Stable in perfumes and diverse functional bases

Other comments :

Comparing it with Methyl Hexyl Ketone, the latter has a more earthy than mushroom smell, as does Methyl Amyl Ketone.

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