Photo credits: ScenTree SAS
Frambinone®
Fruity > Berries > Musky > Dry Woods
Raspberry Ketone® ; 4-(4-hydroxyphenyl)butan-2-one ; 4-(3-oxobutyl)phenol ; Para-hydrobenzyl acetone ; 1-para-hydroxyphenyl-3-butanone ; 4-(4-hydroxyphenyl)-2-butanone ; 1-(4- hydroxyphenyl)-3-butanone ; Para-hydroxyphenylbutanone ; N112 ; N 112 ; Oxanone ; Oxyphenylon ; Rasketone ; Raspberry keytone ; Rastone ; Rheosmin
Photo credits: ScenTree SAS
General Presentation
-
CAS N° :
5471-51-2 -
EINECS number :
226-806-4 -
FEMA number :
2588 -
FLAVIS number :
7,055
-
JECFA number :
728 -
Volatility :
Heart/Base -
Price Range :
€€
Physico-chemical properties
-
Appearance :
White solid -
Density :
N/A -
Refractive Index @20°C :
Donnée indisponible. -
Optical rotation :
Donnée indisponible. -
Vapor pressure :
0,0010 mmHg @20°C -
Flash Point :
94°C (201,2°F)
-
Molecular formula :
C10H12O2 -
Molecular Weight :
164.20 g/mol -
Log P :
0,94 -
Fusion Point :
83°C (181,4°F) -
Boiling Point :
292°C (557,6°F) -
Detection Threshold :
0,1 ppm (0,00001%)
Chemistry & Uses
Uses in perfumery :
Frambinone® brings a fruity evocation in all types of accords. Used in raspberry reconstitutions and other red fruit notes.
Year of discovery :
1918
Natural availability :
Frambinone® is present in several fruits and is extractable in its natural state, but only synthetic Frambinone® is used in perfumery.
Isomerism :
The meta and ortho positional isomers of Frambinone® are not used in perfumery. Styrallyl acetate, Eugenol and Benzyl Propionate are some of the constitutional isomers of Frambinone® that are used in perfumery. Their smell is however very different, as it is fruity-rhubarb, spicy or floral-white flowers.
Synthesis precursor :
Frambinone® is not a precursor to the synthesis of another compound of olfactory interest.
Synthesis route :
Frambinone® is synthesized in two steps. The first is a condensation between 4-hydroxybenzaldehyde and acetone, to obtain 4-hydroxybenzalacetone. A catalytic and selective hydrogenation of the double bond formed allows to obtain the final product, Frambinone®.
Stability :
Stable in perfumes and diverse functional bases
Other comments :
Data not available.
Labelling
Allergens :
This ingredient does not contain any allergen.
Signal word :
Warning
Hazard pictograms :
Precautionary statements :
| HAZARD | PRECAUTION |
|---|---|
| H302 Harmful if swallowed. | P264 Wash ... thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell. P330 Rinse mouth. P501 Dispose of contents/container to… |
IFRA
IFRA 51th :
This ingredient is restricted by the 51th amendment
Quantitative limit on the use :
| Cat.1 | Cat.2 | Cat.3 | Cat.4 |
Cat.5
A
B
C
D
|
Cat.6 | |||
|---|---|---|---|---|---|---|---|---|
| 0,68 % | 1 % | 0,27 % | 1 % |
1 %
0,14 %
0,27 %
0,045 %
|
||||
|
Cat.5
A
B
C
D
|
Cat.6 | |||||||
|
1 %
0,14 %
0,27 %
0,045 %
|
0,82 % | |||||||
|
Cat.7
A
B
|
Cat.8 | Cat.9 |
Cat.10
A
B
|
Cat.11
A
B
|
Cat.12 | |||
|
0,41 %
0,41 %
|
0,045 % | 1 % |
1 %
1 %
|
0,045 %
0,045 %
|
||||
|
Cat.10
A
B
|
Cat.11
A
B
|
Cat.12 | ||||||
|
1 %
1 %
|
0,045 %
0,045 %
|
78 % | ||||||
Contributions from other sources
4-(4-Hydroxyphenyl)butan-2-one has been found in natural extracts but only at trace levels.
Disclaimer :
ScenTree is solely responsible for the information provided here.
To learn more about IFRA's standards : https://ifrafragrance.org/safe-use/library
