Photo credits: ScenTree SAS

Triplal®

Green > Cut Grass > Metallic

Cyclal C® ; Vertocitral® ; Ligustral® ; 2,4-dimethylcyclohex-3-ene-1-carbaldehyde ; Acroval ; Citrulan ; Cyclogreenal ; 2,4-dimethyl-3-cyclohexene-1-carbaldehyde ; 4-formyl-1,3-dimethylcyclohex-1-ene ; Hivertal ; 2,4-ivy carbaldehyde ; Lantral ; Tricyclal ; Trigustral ; Trivertal ; Zestover

Photo credits: ScenTree SAS

Ingredient Name	Learn more	Naturality	MOQ	Purity
TRITAL TR-1	Discover	-	10 grs	-
TRIVERTAL 993135	Discover	Molecules	-	-
Triplal - 30 Gr	Discover	-	30grs	-
SCHIFF LIGUSTRAL 85530	Discover	Molecule	-	-
Ligustral/Triplal	Discover	Synthetic Aroma Chemicals	-	-

TRITAL

TR-1

TRIVERTAL

993135

Triplal - 30 Gr

SCHIFF LIGUSTRAL

85530

Ligustral/Triplal

General Presentation

CAS N° :
68039-49-6
EINECS number :
268-264-1
FEMA number :
4505
FLAVIS number :
Donnée indisponible.

JECFA number :
Donnée indisponible.
Volatility :
Head/Heart
Price Range :
€

Physico-chemical properties

Appearance :
Colorless liquid
Density :
0,937
Refractive Index @20°C :
Donnée indisponible.
Optical rotation :
Donnée indisponible.
Vapor pressure :
0,723 mmHg @23°C
Flash Point :
70°C (158°F)

Molecular formula :
C₉H₁₄O
Molecular Weight :
138,21 g/mol
Log P :
2,34
Fusion Point :
Donnée indisponible.
Boiling Point :
Detection Threshold :
Donnée indisponible.

Chemistry & Uses

Uses in perfumery :

Triplal® is used in jasmine, colognes and fougere notes, to bring a different green and fruity note and freshness. Brings a spring facet to floral notes.

Year of discovery :

1920

Natural availability :

Triplal® is not available in its natural state.

Isomerism :

Triplal® used in perfumery is a mixture of two enantiomers with very similar smells. This is why they are not separated by fractional distillation. Trans-2-cis-6-Nonadienal is a constitutional isomer of Triplal® but has a very different cucumber smell.

Synthesis precursor :

Triplal® forms a Schiff base with Methyl Anthranilate, with a still very green smell but fruity and more artificial.

Synthesis route :

Triplal® is synthesized by a Diels-Alder reaction between 2-methyl-1,3-pentadiene and acrolein. A mixture of two enantiomers is obtained.

Stability :

Aldehydes may form diethylacetals in alcoholic perfumes, with no real impact on their smell.
Very unstable in acid cleaners, antiperspirants and very alkaline products.

Other comments :

In comparision to other cut grass notes, Triplal® has a metallic note that distinguishes it from cis-3-Hexenol for example.

Labelling

Allergens :

This ingredient does not contain any allergen.

Signal word :

Warning

Hazard pictograms :

Precautionary statements :

HAZARD	PRECAUTION
H317 May cause an allergic skin reaction.

IFRA

IFRA 51^th :

This ingredient is restricted by the 51th amendment

Restriction type :
RESTRICTION
Cause of restriction :
DERMAL SENSITIZATION
Amendment :
49

Quantitative limit on the use :

Cat.1	Cat.2	Cat.3	Cat.4	Cat.5 A B C D		Cat.6
0,45 %	0,14 %	2,7 %	2,5 %	0,64 % 0,64 % 0,64 % 0,64 %		1,5 %
Cat.5 A B C D			Cat.6
0,64 % 0,64 % 0,64 % 0,64 %			1,5 %
Cat.7 A B		Cat.8	Cat.9	Cat.10 A B	Cat.11 A B	Cat.12
5,2 % 5,2 %		0,27 %	4,9 %	18 % 18 %	9,8 % 9,8 %	No Restriction
Cat.10 A B	Cat.11 A B	Cat.12
18 % 18 %	9,8 % 9,8 %	No Restriction

Restricted ingredients: notes
The above limits apply to Dimethylcyclohexen-3-ene-1-carbaldehyde (mixed isomers) used individually or in combination. The sum of concentrations of Dimethylcyclohexen-3-ene-1-carbaldehyde isomers should not exceed the maximum concentration levels established by this Standard.

Disclaimer :

ScenTree is solely responsible for the information provided here.

To learn more about IFRA's standards : https://ifrafragrance.org/safe-use/library

Triplal®

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General Presentation

CAS N° :

EINECS number :

FEMA number :

FLAVIS number :

JECFA number :

Volatility :

Price Range :

Physico-chemical properties

Appearance :

Density :

Refractive Index @20°C :

Optical rotation :

Vapor pressure :

Flash Point :

Molecular formula :

Molecular Weight :

Log P :

Fusion Point :

Boiling Point :

Detection Threshold :