Photo credits: ScenTree SAS
Triplal®
Cyclal C® ; Vertocitral® ; Ligustral® ; 2,4-dimethylcyclohex-3-ene-1-carbaldehyde ; Acroval ; Citrulan ; Cyclogreenal ; 2,4-dimethyl-3-cyclohexene-1-carbaldehyde ; 4-formyl-1,3-dimethylcyclohex-1-ene ; Hivertal ; 2,4-ivy carbaldehyde ; Lantral ; Tricyclal ; Trigustral ; Trivertal ; Zestover
Photo credits: ScenTree SAS
| Company | Ingredient Name | ID | Comments | Naturality | Certifications | MOQ | Purity |
|---|---|---|---|---|---|---|---|
|
Triplal - 30 Gr | - |
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|
- | - | - | |
|
SCHIFF LIGUSTRAL | 85530 |
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|
Molecule | - | - |
Triplal - 30 Gr
Certifications :
SCHIFF LIGUSTRAL
ID : 85530
Certifications :
General Presentation
-
CAS N° :
68039-49-6 -
EINECS number :
268-264-1 -
FEMA number :
4505 -
FLAVIS number :
Donnée indisponible.
-
JECFA number :
Donnée indisponible. -
Volatility :
Head/Heart -
Price Range :
€
Physico chemical properties
-
Appearance :
Colorless liquid -
Density :
0,937 -
Refractive Index @20°C :
Data not available. -
Optical rotation :
Data not available. -
Vapor pressure :
0,7228 mmHg @23°C -
Flash Point :
70°C
-
Molecular formula :
C9H14O -
Molecular Weight :
138,21 g/mol -
Log P :
2,34 -
Fusion Point :
Donnée indisponible. -
Boiling Point :
-
Detection Threshold :
Donnée indisponible.
Chemistry & Uses
Uses in perfumery :
Triplal® is used in jasmine, colognes and fougere notes, to bring a different green and fruity note and freshness. Brings a spring facet to floral notes.
Year of discovery :
1920
Natural availability :
Triplal® is not available in its natural state.
Isomerism :
Triplal® used in perfumery is a mixture of two enantiomers with very similar smells. This is why they are not separated by fractional distillation. Trans-2-cis-6-Nonadienal is a constitutional isomer of Triplal® but has a very different cucumber smell.
Synthesis precursor :
Triplal® forms a Schiff base with Methyl Anthranilate, with a still very green smell but fruity and more artificial.
Synthesis route :
Triplal® is synthesized by a Diels-Alder reaction between 2-methyl-1,3-pentadiene and acrolein. A mixture of two enantiomers is obtained.
Stability :
Aldehydes may form diethylacetals in alcoholic perfumes, with no real impact on their smell.
Very unstable in acid cleaners, antiperspirants and very alkaline products.
Other comments :
In comparision to other cut grass notes, Triplal® has a metallic note that distinguishes it from cis-3-Hexenol for example.
Regulations & IFRA
Allergens :
This ingredient does not contain any allergen.
IFRA 51th :
This ingredient is restricted by the 51th amendment
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Restriction type :
RESTRICTION -
Cause of restriction :
DERMAL SENSITIZATION -
Amendment :
49
- Quantitative limit on the use :
-
Cat.1 Cat.2 Cat.3 Cat.4 Cat.5A B C DCat.6 0,45 % 0,14 % 2,7 % 2,5 % 0,64 % 0,64 % 0,64 % 0,64 %1,5 % Cat.5A B C DCat.6 0,64 % 0,64 % 0,64 % 0,64 %1,5 % Cat.7A BCat.8 Cat.9 Cat.10A BCat.11A BCat.12 5,2 % 5,2 %0,27 % 4,9 % 18 % 18 %9,8 % 9,8 %No Restriction Cat.10A BCat.11A BCat.12 18 % 18 %9,8 % 9,8 %No Restriction
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Restricted ingredients: notes
The above limits apply to Dimethylcyclohexen-3-ene-1-carbaldehyde (mixed isomers) used individually or in combination. The sum of concentrations of Dimethylcyclohexen-3-ene-1-carbaldehyde isomers should not exceed the maximum concentration levels established by this Standard.
