Photo credits: ScenTree SAS
Hedione®
Methyl Dihydrojasmonate ; Cepionate® ; MDJ Super® ; Kharismal® ; Methyl 3-oxo-2-pentylcyclopentane acetate ; Claigeon ; Jasmodione ; MDJ ; Methyl (2-pentyl-3-oxocyclopentyl) acetate ; Methyl 2-pentyl-3-oxo-1-cyclopentyl acetate ; Methyl (3-oxo-2-pentylcyclopentyl) acetate ; Supercepionate ; Paradisone®
Photo credits: ScenTree SAS
| Company | Ingredient Name | ID | Comments | Naturality | Certifications | MOQ | Purity |
|---|---|---|---|---|---|---|---|
|
HEDIONE® | 964898 |
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Molecules |
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- | - |
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|
HEDIONE® HC | 947325 |
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Molecules |
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|
Hedione - 30 Gr | - |
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|
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HEDIONE®
ID : 964898
Certifications :
HEDIONE® HC
ID : 947325
Certifications :
Hedione - 30 Gr
Certifications :
General Presentation
-
CAS N° :
24851-98-7 -
EINECS number :
246-495-9 -
FEMA number :
3408 -
FLAVIS number :
09.520
-
JECFA number :
1898 -
Volatility :
Heart -
Price Range :
€€
Physico chemical properties
-
Appearance :
Colorless liquid -
Density :
1,005 -
Refractive Index @20°C :
1,457 - 1,461 -
Optical rotation :
Data not available. -
Vapor pressure :
0,0009 hPa @20°C 0,000245 mmHg @23°C -
Flash Point :
148°C
-
Molecular formula :
C13H22O3 -
Molecular Weight :
226,31 g/mol -
Log P :
2,93 -
Fusion Point :
<20°C -
Boiling Point :
302°C -
Detection Threshold :
Donnée indisponible.
Chemistry & Uses
Uses in perfumery :
Hedione® is used in jasmine reconstitutions, and all kinds of accords, to give volume to the whole, to accompany and give tenacity to the perfume. Allows, in association with Bergamot EO, Beta-Ionone and Damascone-beta, to recreate a tea note for example. Present in a large majority of commercial fragrances.
Year of discovery :
Discovered in 1960, Hedione® was sold at that time for 7500 suiss francs per kilogram. This price really decreased. Patent N°CH382731A published on feb 25, 1960 by Demole.E et Lederer.E for Firmenich et Cie. ''Hedione® '' tradename has been published and protected by Firmenich SA since 04/09/1972 (brand N°392334)
Natural availability :
Hedione® is present in trace amounts in Grandiflorum Jasmine Absolute and in some teas. It is nevertheless exclusively synthetic Hedione® that is used in perfumery.
Isomerism :
Hedione®, commonly used in perfumery, is actually a 9:1 mixture of trans:cis diastereoisomers of the molecule. However, cis-Hedione® is the most powerful isomer. Its detection threshold is seventy times lower than trans-Hedione®. Thus, some Hedione® enriched in cis isomer are marketed: Cepionate® (30% cis), Kharismal® (60% cis) and Hedione® HC (for ''high cis '') (75% cis). Nevertheless, this Hedione® tends to be more unstable than the classic Hedione®, as it isomerizes in its trans form, more stable. Hedione® HC is prepared by a specific distillation technique that involves sodium carbonate. Another method is to hydrogenate the corresponding cyclopenteneacetic acid by a ruthenium II catalysis, followed by a methanol esterification of the acid function.
Synthesis precursor :
The classic Hedione® is a mixture of isomers, it is used to isolate Hedione® HC (High Cis), a superior olfactory quality and power (also to be notes : Cepionate®, Kharismal® and Paradisone®)
Synthesis route :
Hedione® is synthesized from a condensation between cyclopentanone and valeraldehyde, followed by an isomerization of the intermediate product obtained to give 2-pentyl-2-cyclopenten-1-one. This molecule can undergo a Michael addition by reacting it with an alkyl malonate. A hydrolysis followed by a decarboxylation and finally an esterification (using methanol and an acid catalysis) of the acid function that has formed, allows to synthesize the final product, Hedione®.
Stability :
Stable in perfumes and diverse functional bases
Hedione® HC is quite unstable and tends to convert into trans-Hedione®.
Other comments :
Data not available.
Regulations & IFRA
Allergens :
This ingredient does not contain any allergen.
IFRA 51th :
This ingredient is not restricted for the 51th amendment
